Synchrotron radiation studies of the orientation of thin silicon phthalocyanine dichloride film on HOPG substrate

DENG Ju-Zhi; CHEN Rong; SEKIGUCHI Tetsuhiro; BABA Yuji; HIRAO Norie; HONDA Mitsunori

doi:10.1088/1674-1137/32/9/018

Chinese Physics C> 2008, Vol. 32> Issue(9) : 769-772 DOI: 10.1088/1674-1137/32/9/018

Synchrotron radiation studies of the orientation of thin silicon phthalocyanine dichloride film on HOPG substrate

Abstract
HTML
Reference
Related

PDF

Abstract：
Thin silicon phthalocyanine dichloride films on HOPG were prepared and the
sample was heated in the vacuum with laser. The thickness of the thin sample
on HOPG was checked by X-ray photoemission spectroscopy. The orientation of
the molecules in respect to the substrate plane was investigated by measuring the silicon K-edge near edge X-ray absorption fine structure (NEXAFS). In the NEXAFS spectra of the thin sample, two clear peaks which were assigned to 1s→σ_Si-N* and 1s→σ_Si-Cl^* appeared around 1847.2 eV and 1843.1 eV respectively. The intensities of the resonance peaks showed strong polarization dependence. A quantitative analysis of the polarization dependence revealed that the Si-N bond tended to lie down while the Si-Cl bond was out of the molecular plane.

References

[1]

. Friend R H, Gymer R W, Holmes A B et al. Nature(London), 1999, 121: 3972. Dimitrakopoulos C, Malenfant P R L. Adv. Mater (Weinheim,Ger.), 2002, 99: 143. Forrest S R. Chem. Rev., 1996, 97: 17934. Biswas I, Peisert H, Schwieger T et al. J. Chem. Phys.,2005, 122: 0647105. Miao P, Robinson A W, Palmer R E. J. Phys. D, 1998, 31:L376. Michaelis W, Wohrle D, Schlettwein D. J. Mater. Res.,2004, 19: 20407. Ostrick J R, Dodabalapur A, Torsi L et al. J. Appl. Phys.,1997, 81: 68048. Peisert H, Schwiegerm T J, Auerhammerm et al. J. Appl.Phys., 2001, 90: 4669. Vearey-Poberts A R, Steiner H J, Evans S et al. Appl. Surf.Sci., 2004, 234: 13110. Evans D A, Steiner H J, Vearey-Roberts A R et al. Nucl.Instrum. Methods Phys. Res. B, 2003, 199: 47511. Sekiguchi T, Baba Y, Shimoyama I et al. J. Phys.: Condens.Matter, 2005, 17: 545312. Moulder J F, Stichle W F, Sobol P E, Bomben K D. Handbookof X-ray Photoelectron Spectroscopy. Physical ElectronicsInc., Eden Prairie, USA, 199513. Sco eld J H. Physics, 1973, 45: UC-3414. Tanuma S, Powell C J, Penn D R. Surf. Interface Anal.,1994, 21: 16515. Stohr J. in: NEXAFS Spectroscopy. Ed. by G. Ertl, R.Gomer, D.L. Mills, H.K.V. Lotsch. Berlin: Springer-VerlagPress, 1992. 71, 27616. Boo B H, LIU Z Y, Koyano I. J. Phys. Chem. A, 2000, 104:147417. DENG J Z, Baba Y, Sekiguchi T, Hirao N, Honda M J.Phys.:Condens. Matter, 2007, 19: 1118. Outka D A, Stohr J. J. Chem. Phys., 1988, 88: 353919. Kitamura H. Synchrotron Radiation Calculation Programfor PC98, Version 2.3. 1993

[1]	Kai Tang , Bao-Gen Sun , Yong-Liang Yang , Ping Lu , Lei-Lei Tang , Fang-Fang Wu , Chao-Cai Cheng , Jia-Jun Zheng , Hao Li . Transverse beam size measurement system using visible synchrotron radiation at HLS Ⅱ. Chinese Physics C, 2016, 40(9): 097002. doi: 10.1088/1674-1137/40/9/097002
[2]	Qing-Nian Xu , Jian-Fei Tong , Nikolaos Vassilopoulos , Jun Cao , Miao He , Zhi-Long Hou , Han-Tao Jing , Huai-Min Liu , Xiao-Rui Lü , Jing-Yu Tang , Ye Yuan , Guang Zhao , Yang-Heng Zheng . Radiation studies for the MOMENT target station. Chinese Physics C, 2016, 40(12): 126001. doi: 10.1088/1674-1137/40/12/126001
[3]	Zhen-Jie Li , Yun-Cong Jia , Ling-Fei Hu , Peng Liu , Hua-Xiang Yin . Study of silicon pixel sensor for synchrotron radiation detection. Chinese Physics C, 2016, 40(3): 036001. doi: 10.1088/1674-1137/40/3/036001
[4]	HUANG Xi-Yang , JIAO Yi , XU Gang , CUI Xiao-Hao . Suppression of the emittance growth induced by coherent synchrotron radiation in triple-bend achromats. Chinese Physics C, 2015, 39(5): 057001. doi: 10.1088/1674-1137/39/5/057001
[5]	ZHAO Xing , ZHENG Zhong-Shan , LI Bin-Hong , GAO Jian-Tou , YU Fang . Total dose radiation and annealing responses of the backtransistor of Silicon-On-Insulator pMOSFETs. Chinese Physics C, 2015, 39(9): 096101. doi: 10.1088/1674-1137/39/9/096101
[6]	XU De-Rong , XU Hong-Liang , SHAO Yan . Producing terahertz coherent synchrotron radiation atthe Hefei Light Source. Chinese Physics C, 2015, 39(7): 077003. doi: 10.1088/1674-1137/39/7/077003
[7]	ZHANG Yu-Lian , QI Hui-Rong , HU Bi-Tao , FAN Sheng-Nan , WANG Bo , LIU Mei , ZHANG Jian , LIU Rong-Guang , CHANG Guang-Cai , LIU Peng , OUYANG Qun , CHEN Yuan-Bo , YI Fu-Ting . Investigation of GEM-Micromegas detector on X-ray beam of synchrotron radiation. Chinese Physics C, 2014, 38(4): 046001. doi: 10.1088/1674-1137/38/4/046001
[8]	LIU Mei , DAI Hong-Liang , QI Hui-Rong , ZHUANG Bao-An , ZHANG Jian , LIU Rong-Guang , ZHU Qi-Ming , OUYANG Qun , CHEN Yuan-Bo , JIANG Xiao-Shan , WANG Ya-Jie , LIU Peng , CHANG Guang-Cai . Beam test of a one-dimensional position sensitive chamber on synchrotron radiation. Chinese Physics C, 2013, 37(10): 108001. doi: 10.1088/1674-1137/37/10/108001
[9]	XI Shi-Bo , CUI Ming-Qi , ZHU Jing-Tao , YANG Dong-Liang , XU Wei , LIU Li-Juan , GUO Zhi-Ying , ZHAO Jia . An analytical model for the polarization of synchrotron radiation in a soft X-ray region. Chinese Physics C, 2013, 37(3): 038002. doi: 10.1088/1674-1137/37/3/038002
[10]	YANG Dong-Liang , CUI Ming-Qi , WANG Qiu-Ping , ZHAO Yi-Dong , ZHENG Lei , XI Shi-Bo , LIU Li-Juan , GUO Zhi-Ying , WANG De-Lai , LI Chao-Yang , AN Ning . Upgrade of beamline 3W1B at Beijing Synchrotron Radiation Facility. Chinese Physics C, 2013, 37(5): 058001. doi: 10.1088/1674-1137/37/5/058001
[11]	SUN Li-Juan , CUI Ming-Qi , ZHU Jie , ZHAO Yi-Dong , ZHENG Lei , WANG Zhan-Shan , ZHU Jing-Tao . Multilayer-based soft X-ray polarimeter at the Beijing Synchrotron Radiation Facility. Chinese Physics C, 2013, 37(7): 078001. doi: 10.1088/1674-1137/37/7/078001
[12]	SHI Feng , LU Hong , WANG Huan-Yu , MA Yu-Qian , HU Tao , ZHOU Li , CAI Xiao , SUN Li-Jun , YU Bo-Xiang , FANG Jian , XIE Yu-Guang , AN Zheng-Hua , WANG Zhi-Gang , GAO Min , LI Xin-Qiao , XU Yan-Bing , WANG Ping , SUN Xi-Lei , ZHANG Ai-Wu , XUE Zhen , LIU Hong-Bang , WANG Xiao-Dong , ZHAO Xiao-Yun , ZHENG Yang-Heng , MENG Xiang-Cheng , WANG Hui , . Comparative studies of silicon photomultipliers and traditional vacuum photomultiplier tubes. Chinese Physics C, 2011, 35(1): 50-55. doi: 10.1088/1674-1137/35/1/011
[13]	LU Wu , ZHENG Yu-Zhan , WANG Yi-Yuan , REN Di-Yuan , GUO Qi , WANG Zhi-Kuan , WANG Jian-An . Effects of orientation of substrate on the enhanced low-dose-rate sensitivity (ELDRS) in NPN transistors. Chinese Physics C, 2011, 35(2): 169-173. doi: 10.1088/1674-1137/35/2/012
[14]	WANG Dou , QIN Qing , GAO Jie . Study of lower emittance dedicated synchrotron radiation mode for the BEPCⅡ. Chinese Physics C, 2010, 34(11): 1762-1767. doi: 10.1088/1674-1137/34/11/019
[15]	TIAN Shun-Qiang , LIU Gui-Min , LI Hao-Hu , HOU Jie , CHEN Guang-Ling , WAN Cheng-Lan . Nonlinear optimization of the modern synchrotron radiation storage ring based on frequency map analysis. Chinese Physics C, 2009, 33(2): 127-134. doi: 10.1088/1674-1137/33/2/011
[16]	XU Yi , DAI Zhi-Min , LIU Gui-Min . Physics design of SSRF synchrotron radiation security. Chinese Physics C, 2009, 33(S2): 89-92. doi: 10.1088/1674-1137/33/S2/023
[17]	ZHANG Zhe , QIN Xiu-Bo , WANG Dan-Ni , YU Run-Sheng , WANG Qiao-Zhan , MA Yan-Yun , WANG Bao-Yi . Identification of pore size in porous SiO₂ thin film by positron annihilation. Chinese Physics C, 2009, 33(2): 156-160. doi: 10.1088/1674-1137/33/2/015
[18]	GONG Yan , CHEN Bo , NI Qi-Liang , CUI Ming-Qi , ZHAO Yi-Dong , WU Zhong-Hua . Thickness Analysis for Thin-Film by Glazing Exit X-ray Fluorescence With Synchrotron Radiation Source. Chinese Physics C, 2005, 29(11): 1104-1106.
[19]	Wang Jun , Cui Mingqi , Xu Wenxuan , Huang Yuying , Wang Dewu , Liu Jianfei , Xian Dingchang . Study of Multilayer Structures by Synchrotron Radiation with Small Angle Diffraction Method. Chinese Physics C, 1993, 17(S4): 311-319.
[20]	Zhao Jivong , Yang Ping , Jiang Jianhua , Tian Yulian , Han Yong , Wang Chunxi , Shi Caitu , Xian Dingchang . Light Source for Synchrotron Radiation Topographical Study at Beijing Synchrotron Radiation Facility (BSRF). Chinese Physics C, 1992, 16(S3): 235-241.

Access

Get Citation

DENG Ju-Zhi, CHEN Rong, SEKIGUCHI Tetsuhiro, BABA Yuji, HIRAO Norie and HONDA Mitsunori. Synchrotron radiation studies of the orientation of thin silicon phthalocyanine dichloride film on HOPG substrate[J]. Chinese Physics C, 2008, 32(9): 769-772. doi: 10.1088/1674-1137/32/9/018

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2007-10-15
Revised: 2008-01-03

Article Metric

Article Views(3789)
PDF Downloads(664)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synchrotron radiation studies of the orientation of thin silicon phthalocyanine dichloride film on HOPG substrate

Corresponding author: DENG Ju-Zhi,

Received Date: 2007-10-15

Accepted Date: 2008-01-03

Available Online: 2008-09-05

Abstract:

Thin silicon phthalocyanine dichloride films on HOPG were prepared and the
sample was heated in the vacuum with laser. The thickness of the thin sample
on HOPG was checked by X-ray photoemission spectroscopy. The orientation of
the molecules in respect to the substrate plane was investigated by measuring the silicon K-edge near edge X-ray absorption fine structure (NEXAFS). In the NEXAFS spectra of the thin sample, two clear peaks which were assigned to 1s→σ_Si-N* and 1s→σ_Si-Cl^* appeared around 1847.2 eV and 1843.1 eV respectively. The intensities of the resonance peaks showed strong polarization dependence. A quantitative analysis of the polarization dependence revealed that the Si-N bond tended to lie down while the Si-Cl bond was out of the molecular plane.

HTML

Reference (1)

Synchrotron radiation studies of the orientation of thin silicon phthalocyanine dichloride film on HOPG substrate

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article