Local structure and optical absorption characteristic investigationon Fe doped TiO<SUB>2</SUB> nanoparticles

ZHAO Tian-Xing; FENG Ya-Juan; HUANG Jun-Heng; HE Jin-Fu; LIU Qing-Hua; PAN Zhi-Yun; WU Zi-Yu

doi:10.1088/1674-1137/39/2/028001

Chinese Physics C> 2015, Vol. 39> Issue(2) : 028001 DOI: 10.1088/1674-1137/39/2/028001

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles

Abstract
HTML
Reference
Related

PDF

Abstract：
The local structures and optical absorption characteristics of Fe doped TiO₂ nanoparticles synthesized by the sol-gel method were characterized by X-ray diffraction (XRD), X-ray absorption fine structure spectroscopy (XAFS) and ultraviolet-visible absorption spectroscopy (UV-Vis). XRD patterns show that all Fe-doped TiO₂ samples have the characteristic anatase structure. Accurate Fe and Ti K-edge EXAFS analysis further reveal that all Fe atoms replace Ti atoms in the anatase lattice. The analysis of UV-Vis data shows a red shift to the visible range. According to the above results, we claim that substitutional Fe atoms lead to the formation of structural defects and new intermediate energy levels appear, narrowing the band gap and extending the optical absorption edge towards the visible region.

References

[1]

Hashimoto K, Irie H, Fujishima A. Jpn. J. Appl. Phys., 2005, 44: 8269[2] GOU Y Q, CHEN D Y, SU Z X. Appl. Catal. A: General, 2004, 261: 15[3] Di Paola A, Garcia-Lopez E, Ikedab S. Catal. Today, 2002, 75: 87[4] Choi W, Termin A, Hoffmann M R. J. Phys. Chem., 2004,98: 13669[5] Yamashita H, Harada M, Misaka J, Takeuchi M, Neppolian B. Anpo M. Catal. Today, 2003, 84: 191[6] ZHU J F, ZHENG W, HE B, ZHANG J L, Anpo M, Mol J. Catal. A, 2004, 216: 35[7] ZHANG X W, ZHOU M H, LEI L C. Catal. Commun., 2006, 7: 427[8] Anpo M, Takeuchi M. J. Catal., 2003, 216: 505[9] Kato H, Kudo A. J. Phys. Chem. B, 2002, 106: 5029[10] ZHU J F, DENG Z G, CHEN F, ZHANG J L, CHEN H J, HUANG J Z, ZHANG L Z, Anpo M. Appl. Catal. B, 2006, 62: 329[11] Choi W, Termin A, Hoffmann M R. J. Phys. Chem., 1994, 98: 13669[12] ZHU S Y, SHI T F, LIU W H, WEI S Q, XIE Y N, FAN C Z, LI Y Z. Physica B, 2007, 396: 177[13] WU Z, ZHANG J, Ibrahim K, XIAN D C, LI G, TAO Y, HU T D, Bellucci S, Marcelli A, ZHANG Q H, GAO L, CHEN Z Z. Appl. Phys. Lett., 2002, 80: 2973[14] Yadav B C, Verma N, Singh S. Opt. Laser Technol., 2012, 44: 1681[15] Stern E A, Newville M, Ravel B, Rehr J J, Yacoby Y, Haskel D. Physica B, 1995, 208: 154[16] LIU F D, Kiyotaka Asakura, HE H, LIU Y C, SHAN W P, SHI X Y, ZHANG C B. Catal. Today, 2011, 164: 520[17] LIU F D, Kiyotaka Asakura, XIE P Y, WANG J G, HE H. Catal. Today, 2013, 201: 131[18] PAN Z Y, SUN Z H, XIE Z, XU J H, Kojima I, WEI S Q. J. Phys. D: Appl. Phys., 2006, 39: 2796[19] Stengl V, Bakardjieva S. J. Phys. Chem. C, 2010, 114: 19308[20] YU J G, XIANG Q J, ZHOU M H. Appl. Catal. B, 2009, 90: 595[21] ZHU J, REN J, HUO Y, BIAN Z, LI H. J. Phys. Chem. C, 2007, 111: 18965[22] CONG Y, ZHANG J, CHEN F, Anpo M, HE D. J. Phys. Chem. C, 2007, 111: 10618

[1]	LI Yan-Jing , ZHANG Dong-Hai , YAN Shi-Wei , WANG Li-Chun , CHENG Jin-Xia , LI Jun-Sheng . Projectile fragment emission in the fragmentation of ⁵⁶Fe on C, Al and CH₂ targets at 471 A MeV. Chinese Physics C, 2014, 38(1): 014001. doi: 10.1088/1674-1137/38/1/014001
[2]	XIU Qing-Lei , DONG Ming-Yi , LIU Rong-Guang , ZHANG Jian , OUYANG Qun , CHEN Yuan-Bo . Reconstruction algorithm study of 2D interpolating resistive readout structure. Chinese Physics C, 2013, 37(10): 106002. doi: 10.1088/1674-1137/37/10/106002
[3]	LIU Bo , LIU Ran , LI Quan-Jun , YAO Ming-Guang , ZOU Bo , CUI Tian , LIU Bing-Bing , LIU Jing . Study of high pressure structural stability of CeO₂ nanoparticles. Chinese Physics C, 2013, 37(9): 098003. doi: 10.1088/1674-1137/37/9/098003
[4]	CHENG Xue-Rui , DAI Hai-Yang , QI Ze-Ming , WANG Yu-Yin , ZHANG Guo-Bin . Local structure of oxygen-deficient Yttrium oxide. Chinese Physics C, 2013, 37(9): 098002. doi: 10.1088/1674-1137/37/9/098002
[5]	YE Qing , CHEN Xing , ZHOU Jing , ZHAO Hai-Feng , CHU Wang-Sheng , ZHENG Xu-Sheng , WU Zi-Yu . Local hydrated structure of an Fe²⁺/Fe³⁺ aqueous solution: an investigation using a combination of molecular dynamics and X-ray absorption fine structure methods. Chinese Physics C, 2013, 37(3): 038003. doi: 10.1088/1674-1137/37/3/038003
[6]	LIU Chun-Bao , WANG Zhi-Guang . Raman scattering investigation of C-doped a-SiO₂ after high energy heavy ion irradiations. Chinese Physics C, 2011, 35(9): 885-889. doi: 10.1088/1674-1137/35/9/019
[7]	LI Ding . A study on the distribution of adsorbed nanoparticles. Chinese Physics C, 2008, 32(2): 160-164. doi: 10.1088/1674-1137/32/2/017
[8]	LIU Chun-Bao , WANG Zhi-Guang , ZANG Hang , WEI Kong-Fang , YAO Cun-Feng , SHENG Yan-Bin , MA Yi-Zhun , A Benyagoub , M Toulemonde , JIN Yun-Fan . Investigation of PL properties of C-doped SiO₂/Si samples after high energy Pb ion irradiation. Chinese Physics C, 2008, 32(S2): 251-254.
[9]	LIU Miao , QI Ze-Ming , SHI Chao-Shu , XU Mei , ZHANG Wei-Ping , LIU Tao , XIE Ya-Ning . EXAFS Study the Local Structure of Nanocrystalline Lu₂O₃:Eu. Chinese Physics C, 2005, 29(S1): 93-96.
[10]	WANG Jiang-Xue , CHEN Chun-Ying , SUN Jin , YU Hong-Wei , LI Yu-Feng , LI Bai , XING Li , HUANG Yu-Ying , HE Wei , GAO Yu-Xi , CHAI Zhi-Fang , ZHAO Yu-Liang . Translocation of Inhaled TiO2 Nanoparticles Along Olfactory Nervous System to Brain Studied by Synchrotron Radiation X-Ray Fluorescence. Chinese Physics C, 2005, 29(S1): 76-79.
[11]	HONG Xin-Guo , DU Lu-Chao , YE Man-Ping , WENG Yu-Xiang , LI Ming . In Situ Synchrotron Small Angle X-ray Scattering Studies of TiO₂ Colloid at Elevated Temperature. Chinese Physics C, 2003, 27(S1): 63-66.
[12]	Mao Guangjun , Zhao Enguang , Li Zhuxia , Zhuo Yizhong . In-medium △ Absorption Cross Section. Chinese Physics C, 1996, 20(S4): 387-390.
[13]	Huo Lei , Zhang Weining , Wang Shan , Liu Yiming , D. Keane , S. Y. Chu , S. Y. Fung . Absorption Correlation in Pion Interferometry Analyses. Chinese Physics C, 1994, 18(S2): 185-192.
[14]	He Yuanjin , Xin Mingrui , Zhang Tianbao . Measurement of Characteristic Positron Annihilation Lifetime in HgCdTe. Chinese Physics C, 1994, 18(S3): 315-319.
[15]	CHEN Zhiqian . Binding Strength and Oxygen Coordination of the Fe Sites in High T_C GdBa₂ Cu₃O_7—δ. Chinese Physics C, 1993, 17(11): 971-975.
[16]	Chen Zhiqian . Binding Strength and Oxygen Coordination of the Fe Sites in High T_c GdBa₂Cu₃O_7-δ. Chinese Physics C, 1993, 17(S3): 225-229.
[17]	Yu Qingchang . Transformation Groups in Beam Optics (Part 2): Beam Optical Elements and Systems. Chinese Physics C, 1993, 17(S4): 329-333.
[18]	Xu Zizong , Gong Zhufang , Chang Jin , Shi Chaoshu , Shen Dingzhong , Yuan Xianglong , Yin Zhiwen . Fluorescence Properties of Ce³⁺-Doped BaF₂. Chinese Physics C, 1993, 17(S1): 9-16.
[19]	Yu Hong , Shen Qixing . A Study on the Polarization Structure of J/ψ →ωf₂(1270) Decay Process. Chinese Physics C, 1992, 16(S3): 277-280.
[20]	He Zhenmin , Hou Yunzhi . Nuclear Effect on the Nucleon Structure Functions and High P_T Jet Production in p-Fe Collisions. Chinese Physics C, 1988, 12(S3): 245-250.

Access

Get Citation

ZHAO Tian-Xing, FENG Ya-Juan, HUANG Jun-Heng, HE Jin-Fu, LIU Qing-Hua, PAN Zhi-Yun and WU Zi-Yu. Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles[J]. Chinese Physics C, 2015, 39(2): 028001. doi: 10.1088/1674-1137/39/2/028001

RIS(for EndNote,Reference Manager,ProCite)

BibTex

Txt

Milestone

Received: 2014-03-05
Revised: 2014-04-10

Article Metric

Article Views(1983)
PDF Downloads(140)
Cited by(0)

Policy on re-use

To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles

Corresponding author: PAN Zhi-Yun,

Corresponding author: WU Zi-Yu,

Received Date: 2014-03-05

Accepted Date: 2014-04-10

Available Online: 2015-02-05

Abstract: The local structures and optical absorption characteristics of Fe doped TiO₂ nanoparticles synthesized by the sol-gel method were characterized by X-ray diffraction (XRD), X-ray absorption fine structure spectroscopy (XAFS) and ultraviolet-visible absorption spectroscopy (UV-Vis). XRD patterns show that all Fe-doped TiO₂ samples have the characteristic anatase structure. Accurate Fe and Ti K-edge EXAFS analysis further reveal that all Fe atoms replace Ti atoms in the anatase lattice. The analysis of UV-Vis data shows a red shift to the visible range. According to the above results, we claim that substitutional Fe atoms lead to the formation of structural defects and new intermediate energy levels appear, narrowing the band gap and extending the optical absorption edge towards the visible region.

HTML

Reference (1)

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles

Corresponding author: PAN Zhi-Yun,

Corresponding author: WU Zi-Yu,

HTML

目录

Local structure and optical absorption characteristic investigationon Fe doped TiO2 nanoparticles

Abstract：

References

Access

Article Metrics

Metrics

通讯作者: 陈斌, bchen63@163.com

Email This Article

Local structure and optical absorption characteristic investigationon Fe doped TiO2 nanoparticles

Corresponding author: PAN Zhi-Yun,

Corresponding author: WU Zi-Yu,

HTML

目录

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles

Local structure and optical absorption characteristic investigationon Fe doped TiO₂ nanoparticles