Phase transitions in a hydrogen-rich compound:tetramethylsilane

  • High-pressure behavior of tetramethylsilane is investigated by synchrotron powder X-ray diffraction and Raman scattering at pressures up to 30 GPa and room temperature. Our results reveal the analogous phase transitions, though slight hysteresis for the certain phases. A new phase is found to appear at 4.2 GPa due to the disappeared Raman mode. These findings offer the possibility to understand the evolution of the H-H bonding with pressure in such hydrogen-rich compounds.
      PCAS:
  • 加载中
  • [1] Ginzburg V L. Rev. Mod. Phys., 2004, 76: 981-998[2] Ashcroft N W. Phys. Rev. Lett., 1968, 21: 1748-1749[3] Richardson C F, Ashcroft N W. Phys. Rev. Lett., 1997, 78: 118-121[4] Ashcroft N W. Phys. Rev. Lett., 2004, 92: 187002[5] FENG J, Grochala W, JarońT et al. Phys. Rev. Lett., 2006, 96: 017006[6] Pickard C J, Needs R J. Phys. Rev. Lett., 2006, 97: 045504[7] YAO Y, Tse J S, MA Y et al. EPL, 2007, 78: 37003[8] Degtyareva O, Canales M M, Bergara A et al. Phys. Rev. B, 2007, 76: 064123[9] CHEN X J, WANG J L, Struzhkin V V et al. Phys. Rev. Lett., 2008, 101: 077002[10] CHEN X J, Struzhkin V V, SONG Y et al. Proc. Natl. Acad. Sci. USA, 2008, 105: 20-23[11] Eremets M I, Trojan I A, Medvedev S A et al. Science, 2008, 319: 1506-1509[12] Kim D Y, Scheicher R H, Lebégue S et al. Proc. Nat. Acad. Sci. USA, 2008, 105: 16454-16459[13] Martinez-Canales M, Oganov A R, MA Y et al. Phys. Rev. Lett., 2009, 102: 087005[14] Degtyareva O, Proctor J E, Guillaume C L et al. Solid State Commun., 2009, 149: 1583-1586[15] YAN Y, GONG J, ZONG Z G. Chin. Phys. Lett., 2010, 27: 017401[16] Martinez-Canales M, Bergara A, FENG J et al. J. Phys. Chem. Solids, 2006, 67: 2095-2099[17] LI Z, YU W, JIN C. Solid State Commun., 2007, 143: 353-357[18] GAO G, Oganov A R, Bergara A et al. Phys. Rev. Lett., 2008, 101: 107002[19] ZHANG C, CHEN X J, LI Y L et al. J. Supercond. Nov. Magn., 2010, 23: 717-719[20] ZHANG C, CHEN X J, LI Y L et al. EPL, 2010, 90: 66006[21] Tse J S, YAO Y, MA Y. J. Phys.: Condens. Matter, 2007, 19: 425208[22] Tse J S, YAO Y, Tanaka K. Phys. Rev. Lett., 2007, 98: 117004[23] Gonzalez-Morelos P, Hoffmann R, Ashcroft N W. Chem. Phys. Chem., 2010, 11: 3105-3112[24] GAO G, Oganov A R, LI P et al. Proc. Nat. Acad. Sci. USA, 2010, 107: 1317-1320[25] Zaleski-Ejgierd P, Hoffmann R, Ashcroft N W. Phys. Rev. Lett., 2011, 107: 037002[26] Hanfland M, Proctor J E, Guillaume C L et al. Phys. Rev. Lett., 2011, 106: 095503[27] Strobel T A, Goncharov A F, Seagle C T et al. Phys. Rev. B, 2011, 83: 144102[28] Rank D H, Bordner E R. J. Chem. Phys., 1935, 3: 248-251[29] Anderson T F. J. Chem. Phys., 1936, 4: 161-164[30] Silver S. J. Chem. Phys., 1940, 8: 919-933[31] Watari F. Spetrochimica Acta. A, 1978, 34: 1239-1244[32] Shimizu K, Murata H. J. Mol. Spectrosc., 1960, 5: 44-51[33] Young C W, Koehler J S, Mckinney D S. J. Am. Chem. Soc., 1947, 69: 1410-1415[34] Hoffman R E. Magn. Reson. Chem., 2006, 44: 606-616[35] Wolf A K, Glinnemann J, Fink L et al. Acta Cryst. B, 2010, 66: 229-236[36] Gajda R, Katrusiak A. Cryst. Growth Des., 2008, 8: 211-214[37] QIN Z X, ZHANG J B, Troyan I. J. Chem. Phys., 2012, 136: 024503[38] Larson A C, Von-Dreele R B. GSAS-General Strcture Analysis System. Report LAUR 86-748. Los Alamos National Laboratory, USA, 1994[39] LIN Y, MAO W L, Drozd V et al. J. Chem. Phys., 2008, 129: 234509[40] Adams D M Pogson M. J. Phys. C, 1988, 21: 1065-1079[41] Rush J J, Hamilton W C. Inorg. Chem., 1966, 5: 2238-2239[42] Adams D M, Haines J. Spectrochim. Acta, Part A, 1993, 49: 237-248[43] Strobel T A, Somayazulu M, Hemley R J. Phys. Rev. Lett., 2009, 103: 065701[44] WANG S B, MAO H K, CHEN X J et al. Proc. Natl. Acad. Sci. USA, 2009, 106: 14763-14767[45] LI Y W, GAO G Y, XIE Y et al. Proc. Natl. Acad. Sci. USA, 2010, 107: 15708-15711[46] Yim W L, Tse J S, Iitaka T. Phys. Rev. Lett., 2010, 105: 215501[47] Michel K, LIU Y D, Ozolins V. Phys. Rev. B, 2010, 82: 174103[48] Strobel T A, CHEN X J, Somayazulu M et al. J. Chem. Phys., 2010, 133: 164512[49] ZHONG G H, ZHANG C, CHEN X J et al. J. Phys. Chem. C, 2012, 116: 5225-5234
  • 加载中

Get Citation
QIN Zhen-Xing, TANG Ling-Yun, LIU Jing and CHEN Xiao-Jia. Phase transitions in a hydrogen-rich compound:tetramethylsilane[J]. Chinese Physics C, 2013, 37(9): 098001. doi: 10.1088/1674-1137/37/9/098001
QIN Zhen-Xing, TANG Ling-Yun, LIU Jing and CHEN Xiao-Jia. Phase transitions in a hydrogen-rich compound:tetramethylsilane[J]. Chinese Physics C, 2013, 37(9): 098001.  doi: 10.1088/1674-1137/37/9/098001 shu
Milestone
Received: 2012-10-16
Revised: 2013-04-09
Article Metric

Article Views(1747)
PDF Downloads(274)
Cited by(0)
Policy on re-use
To reuse of subscription content published by CPC, the users need to request permission from CPC, unless the content was published under an Open Access license which automatically permits that type of reuse.
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

Email This Article

Title:
Email:

Phase transitions in a hydrogen-rich compound:tetramethylsilane

    Corresponding author: CHEN Xiao-Jia,

Abstract: High-pressure behavior of tetramethylsilane is investigated by synchrotron powder X-ray diffraction and Raman scattering at pressures up to 30 GPa and room temperature. Our results reveal the analogous phase transitions, though slight hysteresis for the certain phases. A new phase is found to appear at 4.2 GPa due to the disappeared Raman mode. These findings offer the possibility to understand the evolution of the H-H bonding with pressure in such hydrogen-rich compounds.

    HTML

Reference (1)

目录

/

DownLoad:  Full-Size Img  PowerPoint
Return
Return